Characterized by the excelent UV transmission, high damage threshold,
and high birefringence, KDP (Potassium Dihydrogen Phosphate) are commonly used commercial NLO materials
for doubling, tripling and quadrupling of Nd:YAG laser at room
temperature or an elevated temperature. KDP are also excellent
electro-optic (EO) crystals with high EO coefficients, thus popularly
used as EO modulators and Pockels cells for Q-switched
lasers.
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KDP (KH2PO4 ) and DKDP/KD*P (KD2PO4 ) are among the most widely-used commercial NLO materials. With good UV transmission, high damage threshold, and high birefringence, these material are usually used for doubling, tripling and quadrupling of Nd:YAG laser. With high E-O coefficient, KDP and DKDP crystals are also widely used to make Pockels cells for laser system, such as Nd:YAG, Nd:YLF, Ti-Sapphire, Alexandrite, etc.
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Potassium
Dihydrogen Phosphate (KDP) and Potassium Dideuterium Phosphate (DKDP)
are among the most widely-used commercial NLO materials, characterized
by good UV transmission, high damage threshold, and high birefringence,
though their NLO coefficients are relatively low. They are usually used
for doubling, tripling or quadrupling of a Nd:YAG laser (at constant
temperature).
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Characterized by the excelent UV transmission, high damage threshold,
and high birefringence, KDP (Potassium Dihydrogen Phosphate) and KD*P
(Potassium Dideuterium Phosphate) are useful commercial NLO materials
for doubling, tripling and quadrupling of Nd:YAG laser at room
temperature or an elevated temperature. They are also excellent
electro-optic (EO) crystals with high electro-optic coefficients, widely
used as electro-optical modulators and Pockels cells for Q-switched
lasers.
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Readily available stock of periodically poled LN (PPLN) crystals can be provided
on short lead time, with various specifications of sizes and periods.PPLN SHG crystals are available for pump
laser wavelengths 976-2100 nm, generating light 488-1050nm.PPLN OPO crsytals are available for pump sources 515-1064 nm, generating visible
and IR CW beams.PPLN DFG crystals are available for various combinations of pump sources, generating wavelengths 2-5.5 um.PPLN SFG crystals are available for various combinations of pump
sources, generating wavelengths 500-700 nm.
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BBO is an effective NLO crystal for the SHG, THG, or FHG of Nd:YAG lasers, and the first-rate NLO crystal for the FHG at 213nm. Conversion efficiencies of more than 70% for SHG, 60% for THG and 50% for 4HG, and 200mw output at 213 nm (5HG) have been obtained through using Wisoptic's BBO, respectively.BBO is also an efficient crystal for the intracavity SHG of excessive energy Nd:YAG lasers. for the intracavity SHG of an acousto-optic Q-switched Nd:YAG laser, greater than 15 w average power at 532 nm generated via an AR-coated BBO crystal produced by Wisoptic.
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Potassium Dihydrogen Phosphate (KDP) and Potassium Dideuterium Phosphate (KD*P, DKDP) crystals are among the most widley used nonlinear crystals. Both of these crystals are routinely used for the doubling, triplingand quadrupling of Nd:YAG lasers at room temperatures.
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Readily available stock of periodically poled MgO:LN crystals can be provided
on short timescales to rapidly meet your application needs, providing
the capability to efficiently generate laser light in a wide range of
wavelengths.MgO:PPLN SHG crystals are available for a wide range of common pump
laser wavelengths from 976 nm to 2100 nm, allowing generation of light
between 488nm and 1050nm.MgO:PPLN OPO are available for 515nm and 1064nm pump sources, allowing
continuous wavelength generation in a selection of ranges in the visible
and IR.MgO: PPLN DFG Crystals are available for
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Beta-BBO crystal is an important nonlinear optical crystal
with combination of unique optical properties, such as broad transmission and
phase matching ranges, large nonlinear coefficient, high damage
threshold and excellent optical homogeneity. The β-BBO crystal is an efficient material for the second, third and fourth
harmonic generation of Nd:YAG lasers, and the best NLO material for the
fifth harmonic generation at 213 nm.
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KTP Crystal Features• Large Nonlinear Optical (NLO) Coefficients• Wide Phase-matching Acceptance Angle• Broad Temperature and Spectral Bandwidth• High Electro-Optic (E-O) Coefficients
• Nonhygroscopic, Good Chemical and Mechanical Properties
• Relatively High Damage Threshold for E-O modulatorKTP Crystal Applications1. SHG of Nd:Laser - KTP is the most commonly used material for
frequency doubling of Nd:YAG and other Nd-doped lasers, particularly
when the power density is at a low or medium level.
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Diffusion Bonded Crystal (DBC) is a crystalline solid used
in photo optic applications. It consists of two, three or more parts of crystals with different dopants or same dopant with different doping levels. This material is commonly made by bonding one laser crystal with one or two undoped crystals by precise optical contact and further processing under high temperature.
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KTP Pockels are based on hydrothermal-grown high resistivity KTP crystals overcomes the common
electrochromism damage of flux-grown KTP. Hydrothermal-grown KTP crystals have better optical homogeneity and higher damage threshold
comparing to RTP crystals. This KTP crystal has large effective electro-optic coefficients and lower
half-wave voltage. The Q-switch is built utilizing thermally compensated
double crystal designs.
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Nominally pure stoichiometric LiNbO3
shows lower photorefractive damage resistance than congruent crystal;
however, stoichiometric crystals doped with MgO of more than 1.8 mol.
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LiNbO3 (Lithium Niobate, LN) crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability.Among the EO crystals, LN and DKDP are the two primary material that have been practical. DKDP crystals can be easily grown with a high optical homogeneity, which can satisfy the requirement of a large caliber Pockels cell.
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Gray Track Resistant (GTR) KTP crystals developed by hydrothermal method overcomes the common phenomenon of
electrochromism of the flux-grown KTP, thus has many advantages such as
high electrical resistivity, low insertion loss, low half-wave voltage,
high laser damage threshold, and wide transmission band. So it's very suitable for high power density
applications, where regular flux-grown KTP crystals will suffer from
gray track damage.GTR-KTP crystal has gray track resistance sufficiently greater than
typical flux-grown KTP.
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Tm:YAP crystal is one of the most important crystals for LD pumping 2μm laser. The anisotropic structure of Tm:YAP produces anisotropic emission cross section. Tm:YAP crystals with different orientations have different output wavelengths and operating forms for different functions. Compared with the physical and chemical properties of Tm:YAG, the 795nm pump absorption band of Tm:YAP matches the emission wavelength of commonly used high-power AlGaAs diodes better.
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Nd:YAG (Neodymium Doped Yttrium Aluminum Garnet, Nd:Y3Al5O12) has been and continues to be the most mature and most widely used crystals for lasers, no matter solid state or lamp pumped, CW or pulsed. It possesses a combination of properties uniquely favorable for laser operations. Nd:YAG
crystals are used in all types of solid-state lasers
systems-frequency-doubled continuous wave, high-energy Q-switched, and
so on.
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Diffusion bonded crystal consists of two, three or more parts of crystals with different dopants or same dopant with different doping levels. This material is commonly made by bonding one laser crystal with one or two undoped crystals by precise optical contact and further processing under high temperature.
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LiNbO3 (Lithium Niobate, LN) crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability. Among the EO crystals, LN and DKDP are the two primary material that have been practical. DKDP crystals can be easily grown with a high optical homogeneity, which can satisfy the requirement of a large caliber Pockels cell.
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Potassium dideuterium phosphate DKDP (KD * P) crystal has low optical loss, high extinction ratio, and excellent electro-optical performance. DKDP Pockels cells are made by using the longitudinal effect of DKDP crystals. The modulation effect is stable and the pulse width is small.
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One of the most important drawbacks of popular LiNbO3 crystal is its
susceptibility to photorefractive damage (optically induced change of
refractive index, usually under exposure with blue or green CW light).
The usual way to eliminate this effect is to keep LN crystals at
elevated temperatures (400K or more). Another way to prevent
photorefractive damage is MgO-doping (usually at levels of around 5 mol%
for congruent LN).
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Compared with congruent LN (cLN) crysal, the electro-optic
coefficient, nonlinear optical coefficient, periodic polarization
reversal voltage and applied photorefractive properties of
stoichiometric LN (sLN) crystal are greatly improved. With such excellent
physical properties and wide application prospects, sLN crystal has rapidly become a competitive optoelectronic
material.sLN crystals are expected to be thermodynamically stable up to their melting temperature at 1170°C, while keeping a largerelectrical resistivity than cLN crystals by one order of magnitude at any temperature.
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E-O Q-switch based on DKDP (KD*P) crystals are one of the most popular Pockels cells in the market.Deuterated potassium dihydrogen phosphate has good transmission from
390 nm to 1400 nm (0.39 μm – 1.4 μm) and combined with high
electro-optical coefficients makes it suitable for Pockels cells.Highly deuterated DKDP
(D>99% – WISOPTIC) is necessary to reach effective electro-optical
response.
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High temperature phase of α-BBO Crystal (BaB2O4)
is one of the excellent birefringent crystals. It is characterized by
large birefringent coefficient and wide transmission window ranged from
189nm to 3500nm. Due to its high chemical stability and medium hardness,
α-BBO is fabricated easily into many kinds of optical components.The
physical, chemical, thermal and optical properties of α-BBO are similar
to those of β-BBO.
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