One of the most important drawbacks of popular LiNbO3 crystal is its
susceptibility to photorefractive damage (optically induced change of
refractive index, usually under exposure with blue or green CW light).
The usual way to eliminate this effect is to keep LN crystals at
elevated temperatures (400K or more). Another way to prevent
photorefractive damage is MgO-doping (usually at levels of around 5 mol%
for congruent LN).
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LN crystals are nonhygroscopic and have low absorption coefficient and insert loss. In addition, LN crystal can operate stably in a wide temperature range, which makes them the main EO crystal applied in military laser systems.LN electro-optic Q-switches are widely
used in Er:YAG, Ho:YAG, Tm:YAG lasers, and are suitable for low-power
Q-switched output, especially in laser ranging. LN Pockels cells can be very compact, and the half-wave voltage can be very low. By doping MgO in LiNbO3, the damage threshold of LN Pockels cells can been increased dramatically.
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Nominally pure stoichiometric LiNbO3
shows lower photorefractive damage resistance than congruent crystal;
however, stoichiometric crystals doped with MgO of more than 1.8 mol.
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Lithium
Niobate (LiNbO3) is widely used in fiber communication devices as birefringent
crystal and used as electro-optic modulator and Q-switch
for Nd:YAG, Nd:YLF and Ti:Sapphire lasers. It has good mechanical and physical properties and is ideal for optical
polarizing components due to its wide transparency range and low cost. LiNbO3's applications for fiber communication include isolators, circulators, beam displacers, and other polarizing
optics. The transverse modulation is mostly employed for
LiNbO3 crystal.
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LN Crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability.As one of the most thoroughly characterized nonlinear optical materials, LiNbO3 is suitable for a variety of frequency conversion applications. For example, it is widely used as frequency doublers for wavelength >1 μm and optical parametric oscillators (OPOs) pumped at 1064 nm as well as quasi-phase-matched (QPM) devices.
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Lithium Niobate (LN) crystal has excellent electro-optic, acousto-optic, piezoelectric and nonlinear properties. More and more attention has been paid on its application in military technology. LN crystal has large nonlinear optical coefficient and can easily achieve non-critical phase matching. As an E-O material, LN crystal has been used as an important optical waveguide material.
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Pure LiNbO3 (LN) is a good candidate for various optical devices, but
has a major disadvantage due to its low threshold optical damage. MgO:LN (congruent
compositions) is one of the possible solutions to deal with this
problem. MgO doping has played an important role in LN and shown an
increased threshold laser beam strength by 100 times. An interesting
point is that every physical property of MgO:LN (e.g.
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LiNbO3 crystal is a low cost photoelectric material with good mechanical
and physical properties as well as high optical homogeneity. It has
been widely used as frequency doublers for wavelength > 1mm and
optical parametric oscillators (OPOs) pumped at 1064nm as well as
quasi-phase-matched (QPM) devices. With preferable E-O coefficients,
LiNbO3 crystal has become the most commonly used material for Q-switches
and phase modulators, waveguide substrate, and surface acoustic wave
(SAW) wafers, etc.
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LiNbO3 (Lithium Niobate, LN) crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability. Among the EO crystals, LN and DKDP are the two primary material that have been practical. DKDP crystals can be easily grown with a high optical homogeneity, which can satisfy the requirement of a large caliber Pockels cell.
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LiNbO3 (Lithium Niobate, LN) crystal is a multifunctional material that integrates properties of piezoelectric, ferroelectric, pyroelectric, nonlinear, electro-optical, photoelastic, etc. LiNbO3 has good thermal stability and chemical stability.Among the EO crystals, LN and DKDP are the two primary material that have been practical. DKDP crystals can be easily grown with a high optical homogeneity, which can satisfy the requirement of a large caliber Pockels cell.
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The high
damage threshold makes BBO cells more attractive than others in the high
power systems. Like LiNbO3 Pockels cells, BBO Pockels cells work in
transverse mode, which makes the cells very compact, and the half-wave
voltage designable. BBO Pockels cells are also suitable for systems with
high repetition rates.WISOPTIC has been granted of several patents for its technology of BBO Pockels cells. WISOPTIC’s mass products of BBO Pockels cell are gaining worldwide customers’ interest and trust for its high cost performance.
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The periodic polarized KTP (PPKTP) is a novel nonlinear optical material that can be customized to achieve all of the nonlinear applications required in the entire KTP crystal transmission band, without the phase matching limitations of conventional KTP. Moreover, the effective nonlinear coefficient of PPKTP is about 3 times higher than that of conventional KTP. In the nonlinear application of conventional KTP, the crystal must have a single domain structure, but PPKTP crystal has an artificially induced periodic domain structure.
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LBO (LiB3O5) is a kind of non-linear optical crystal with good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). So LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.LBO has large band gap and transparency region, high non-linear coupling, good chemical and mechanical properties.
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Beta-BBO crystal is an important nonlinear optical crystal
with combination of unique optical properties, such as broad transmission and
phase matching ranges, large nonlinear coefficient, high damage
threshold and excellent optical homogeneity. The β-BBO crystal is an efficient material for the second, third and fourth
harmonic generation of Nd:YAG lasers, and the best NLO material for the
fifth harmonic generation at 213 nm.
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Compared with congruent LN (cLN) crysal, the electro-optic
coefficient, nonlinear optical coefficient, periodic polarization
reversal voltage and applied photorefractive properties of
stoichiometric LN (sLN) crystal are greatly improved. With such excellent
physical properties and wide application prospects, sLN crystal has rapidly become a competitive optoelectronic
material.sLN crystals are expected to be thermodynamically stable up to their melting temperature at 1170°C, while keeping a largerelectrical resistivity than cLN crystals by one order of magnitude at any temperature.
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Nd:YLF is an excellent crystal that is very suitable for working in mode-locked mode to obtain short pulse laser. Nd:YLF has very small thermal lens effect (much smaller than YAG crystal), wide fluorescent line, and can generate linear-polarized beam. The relatively small stimulated emission cross section of Nd:YLF makes it suitable for continuous work with low threshold. Nd:YLF crystal has obtained important applications in inertial confinement laser fusion research projects.
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Diffusion bonded crystal consists of two, three or more parts of crystals with different dopants or same dopant with different doping levels. This material is commonly made by bonding one laser crystal with one or two undoped crystals by precise optical contact and further processing under high temperature.
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LBO (LiB3O5) is a kind of non-linear optical crystal with good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). So LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.LBO has large band gap and transparency region, high non-linear coupling, good chemical and mechanical properties.
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Barium Borate exists in three major crystalline forms: alpha, beta, and
gamma. The low-temperature beta phase converts into the alpha phase upon
heating to 925 °C. β-BBO differs from α-BBO by the
positions of the barium ions within the crystal. Both phases are
birefringent, however α-BBO has centric symmetry and thus
does not has the same nonlinear properties as β-BBO.α-BBO is a negative uniaxial crystal with a large birefringence over the broad transparent range from 189 nm to 3500 nm.
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Tm:YAP crystal is one of the most important crystals for LD pumping 2μm laser. The anisotropic structure of Tm:YAP produces anisotropic emission cross section. Tm:YAP crystals with different orientations have different output wavelengths and operating forms for different functions. Compared with the physical and chemical properties of Tm:YAG, the 795nm pump absorption band of Tm:YAP matches the emission wavelength of commonly used high-power AlGaAs diodes better.
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KTA (Potassium Titanyle Arsenate, KTiOAsO4 ) is a nonlinear optical crystal similar to KTP in which atom P is replaced by As. It has good non-linear optical and electro-optical properties, e.g.
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KTA (Potassium Titanyle Arsenate, KTiOAsO4 ) is a nonlinear optical crystal similar to KTP in which atom P is replaced by As. It has good non-linear optical and electro-optical properties, e.g.
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RTP (RbTiOPO4) is an isomorph of KTP crystal. RTP has many advantages e.g. large nonlinear optical coefficient, large E-O coefficient, high damage threshold (about 1.8 times of KTP), high resistivity, high repetition rate, no hygroscopy and no induced piezo-electric effect with electrical signals up to 60 kHz. The transmission range of RTP is 350 nm to 4500 nm.RTP crystal is widely used in laser Q-switching system with high frequency repetition, high power and narrow pulse width.
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Nd:YVO4 (Neodymium-doped Yttrium Vanadate) is the most efficient laser crystal for diode-pumped solid-state lasers. Its good physical, optical and mechanical properties make Nd:YVO4 an excellent crystal for high power, stable and cost-effective diode-pumped solid-state lasers, especially for lasers with low or middle power density. Nd:YVO4 is
a good choice for highly polarized output at 1342 nm, as the emission
line is much stronger than those of its alternatives.
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